1-Hydroxymethyl-3,12-dioxa-14-aza-tetracyclo[9.2.1.0.0]tetradecane.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, People's Republic of China.

Published: March 2008

In the title fused-ring compound, C(12)H(13)NO(3), the two five-membered C(3)NO rings both approximate to envelope conformations with C atoms in the flap positions. The OH group of the pendant CH(2)OH unit is disordered over two positions in a 0.528 (5):0.472 (5) ratio. One of the OH groups participates in an O-H⋯N hydrogen bond, generating centrosymmetric dimers in the crystal structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960989PMC
http://dx.doi.org/10.1107/S1600536808007976DOI Listing

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The title compound, (C(10)H(28)N(4))[MnCl(4)(H(2)O)(2)]Cl(2)·2H(2)O, consists of isolated octa-hedral [MnCl(4)(H(2)O)(2)](2-) anions, tetra-protonated 1,4,8,11-tetra-azoniacyclo-tetradecane cations, chloride anions and water mol-ecules connected by a network of hydrogen bonds. The Mn(II) atom is situated on an inversion centre, and the 1,4,8,11-tetra-azoniacyclo-tetradecane cation is located on a mirror plane.

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1-Hydroxymethyl-3,12-dioxa-14-aza-tetracyclo[9.2.1.0.0]tetradecane.

Acta Crystallogr Sect E Struct Rep Online

March 2008

Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, People's Republic of China.

In the title fused-ring compound, C(12)H(13)NO(3), the two five-membered C(3)NO rings both approximate to envelope conformations with C atoms in the flap positions. The OH group of the pendant CH(2)OH unit is disordered over two positions in a 0.528 (5):0.

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