In the title salt, C(23)H(26)N(4) (2+)·2C(6)H(2)N(3)O(7) (-), the dihedral angle between the imidazolium rings in the dication is 69.9 (1)°. The aromatic ring of the benzyl group is almost perpendicular to the N-heterocyclic ring that is directly connected to it [dihedral angles = 83.2 (2) and 77.3 (3)°].
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961014 | PMC |
| http://dx.doi.org/10.1107/S1600536808006272 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Synthesis, crystal growth and physiochemical characterization of organic NLO crystal: L-ornithinium dipicrate (LODP).
Spectrochim Acta A Mol Biomol Spectrosc
February 2015
Department of Physics, School of Physics, Madurai Kamaraj University, Madurai 625021, Tamil Nadu, India.
L-ornithinium dipicrate (LODP) has been synthesized and good quality single crystals were grown by slow evaporation method at room temperature. Single crystal XRD confirms that the grown crystal belongs to the monoclinic system with the noncentrosymmetric space group P21. Powder X-ray diffraction study confirms the crystalline nature of the compound.
View Article and Find Full Text PDFCarbinoxaminium dipicrate.
Acta Crystallogr Sect E Struct Rep Online
October 2013
Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India.
In the dication of the title salt, C16H21ClN2O(2+)·2C6H2N3O7 (-) [systematic name: 2-{(4-chloro-phen-yl)[2-(di-methyl-aza-nium-yl)eth-oxy]meth-yl}pyridinium bis-(2,4,6-tri-nitro-phenolate), contains a carbinoxaminium dication and two picrate anions, which are held together through inter-molecular N-H⋯O hydrogen bonds. In the dication, the two aromatic rings form a dihedral angle of 80.1 (1)°.
View Article and Find Full Text PDFStructure and spectral properties of L-histidinium dipicrate dihydrate.
Spectrochim Acta A Mol Biomol Spectrosc
January 2014
Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore 641 020, Tamil Nadu, India.
Non-linear optical active L-histidinium dipicrate dihydrate (LHDD) single crystals were grown by slow evaporation method. The Fourier transform FT-IR, FT-Raman, (1)H and (13)C NMR spectra of the crystal have been recorded and analysed. The spectral analyses confirm the formation of the compound and the stoichiometry.
View Article and Find Full Text PDFl-Histidinium dipicrate dihydrate.
Acta Crystallogr Sect E Struct Rep Online
June 2013
Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore 641 020, Tamil Nadu, India.
In the title mol-ecular salt, C6H11N3O2 (2+)·2C6H2N3O7 (-)·2H2O, the histidine mol-ecule exists as a histidinium dication, being protonated at the N atom of the imidazole ring. The charges are balanced by two picrate anions and the compound crystallizes as a dihydrate. In the crystal, the components are linked via N-H⋯O and O-H⋯O hydrogen bonds and weak C-H⋯O inter-actions, forming a three-dimensional supermolecular structure.
View Article and Find Full Text PDFOlanzapinium dipicrate.
Acta Crystallogr Sect E Struct Rep Online
February 2013
Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India.
THE ASYMMETRIC UNIT OF THE TITLE SALT [SYSTEMATIC NAME: 2-methyl-4-(4-methyl-piperazin-4-ium-1-yl)-10H-thieno[2,3-b][1,5]benzodiazepinium bis-(2,4,6-trinitro-phenolate)], C(17)H(22)N(4)S(2+)·2C(6)H(2)N(3)O(7) (-), consists of a diprotonated olanzapinium cation and two independent picrate anions. In the cation, the piperazine ring adopts a distorted chair conformation and contains a positively charged N atom with quaternary character and the N atom in the seven-membered 1,5-diazepine ring, which adopts a boat configuration, is also protonated. The dihedral angle between the benzene and thiene rings flanking the diazepine ring is 58.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!