1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine.

Acta Crystallogr Sect E Struct Rep Online

Published: February 2008

In the crystal structure of the title compound, C(22)H(17)N(3)O, the oxazine ring has a half-chair conformation. The dihedral angles between the best least-squares plane through the pyridine rings and the planar part (O-C-C-C-N) of the oxazine ring are 72.14 (6) and 35.44 (7)°, the smaller angle involving the pyridine ring adjacent to the oxazine O atom. The mol-ecule has two stereogenic centers at the oxazine carbons, RS and SR. The crystal packing reveals that symmetry-related mol-ecules are linked by inter-molecular N-H⋯N hydrogen bonds to form chains parallel to the b axis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960797PMC
http://dx.doi.org/10.1107/S1600536808003887DOI Listing

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