In the mol-ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the mol-ecule is essentially planar. The intra-molecular O-H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules to form parallel networks. There is a C-H⋯π contact between the methyl group and the benzene ring. A π-π contact between the benzene and phenyl rings [centroid-centroid distance = 4.681 (5) Å] is also observed.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960573 | PMC |
| http://dx.doi.org/10.1107/S1600536808026883 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Crystal structure of (E)-4-meth-oxy-2-{[(5-methyl-pyridin-2-yl)imino]-meth-yl}phenol.
Acta Crystallogr E Crystallogr Commun
November 2015
School of Chemical Sciences, 11800, USM Pulau Pinang, Malaysia.
The mol-ecule of the title Schiff base compound, C14H14N2O2, displays an E conformation with respect the imine C=N double bond. The mol-ecule is approximately planar, with the dihedral angle formed by the planes of the pyridine and benzene rings being 5.72 (6)°.
View Article and Find Full Text PDF4-Meth-oxy-2-{(E)-[(thio-phen-2-yl)methyl-imino]-meth-yl}phenol.
Acta Crystallogr Sect E Struct Rep Online
September 2012
The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol-imine tautomeric form and reveals an intra-molecular O-H⋯N hydrogen bond involving the hy-droxy group and the imino N atom, forming an S(6) ring. The mol-ecule is highly twisted with respect to the central imine group, which is reflected in the dihedral angle of 67.83 (10)° formed by the thienyl and phenol rings.
View Article and Find Full Text PDF(E)-4-Meth-oxy-2-(p-tolyl-imino-meth-yl)phenol.
Acta Crystallogr Sect E Struct Rep Online
January 2010
The mol-ecule of the title compound, C(15)H(15)NO(2), adopts the enol-imine tautomeric form and has a strong intra-molecular O-H⋯N hydrogen bond as a result. The mol-ecule is almost planar, with a maximum deviation of 0.1038 (15) Å for the meth-oxy C atom.
View Article and Find Full Text PDF(E)-4-Meth-oxy-2-(o-tolyl-imino-meth-yl)phenol.
Acta Crystallogr Sect E Struct Rep Online
March 2009
In the mol-ecule of the title compound, C(15)H(15)NO(2), the aromatic rings are oriented at a dihedral angle of 15.46 (6)°. An intra-molecular O-H⋯N hydrogen bond results in the formation of a nearly planar six-membered ring [maximum deviation of 0.
View Article and Find Full Text PDF(E)-4-Meth-oxy-2-[3-(trifluoro-meth-yl)phenyl-imino-meth-yl]phenol.
Acta Crystallogr Sect E Struct Rep Online
November 2009
The title compound, C(15)H(12)F(3)NO(2), adopts the phenol-imine tautomeric form, with the H atom attached to oxygen rather than to nitro-gen. There are two independent mol-ecules aligned nearly parallel in the asymmetric unit with their trifloramethyl groups pointing in opposite directions. The dihedral angles between the aromatic rings are 40.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!