catena-Poly[[[diaqua-cobalt(II)]bis-(μ-1,3-di-4-pyridylpropane-κN:N')] bis-(perchlorate) bis-(1,3-di-4-pyridyl-propane) bis-(2-methyl-4-nitro-aniline)].

Acta Crystallogr Sect E Struct Rep Online

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, People's Republic of China.

Published: August 2008

In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa-hedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol-ecule, one 2-methyl-4-nitro-aniline mol-ecule and one perchlorate anion. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960494PMC
http://dx.doi.org/10.1107/S1600536808026470DOI Listing

Publication Analysis

Top Keywords

13-di-4-pyridylpropane ligands
8
one-dimensional chains
8
catena-poly[[[diaqua-cobaltii]bis-μ-13-di-4-pyridylpropane-κnn'] bis-perchlorate
4
bis-perchlorate bis-13-di-4-pyridyl-propane
4
bis-13-di-4-pyridyl-propane bis-2-methyl-4-nitro-aniline]
4
bis-2-methyl-4-nitro-aniline] title
4
title compound
4
compound {[coc13h14n22h2o2]clo42·2c13h14n2·2c7h8n2o2}n
4
{[coc13h14n22h2o2]clo42·2c13h14n2·2c7h8n2o2}n coii
4
coii ion
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!