The title dinuclear platinum compound, [Pt(2)Cl(4)(C(22)H(16)N(4))(C(2)H(6)S)(2)], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt(II) cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are trans to each other, with a Cl-Pt-Cl angle of 178.83 (8)°. The pyridine ring forms a dihedral angle of 48.8 (2)° with the planar PtCl(2)SN unit. Within the mol-ecule, the distance between Pt atoms is 20.262 (5) Å and the N⋯N separation between the terminal pyridyl rings is 16.23 (1)Å.
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| http://dx.doi.org/10.1107/S1600536808024914 | DOI Listing |
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