Bis{μ-5-(diethyl-amino)-2-[(2-oxidoeth-oxy)imino-meth-yl]phenolato}dicopper(II) acetone solvate.

Acta Crystallogr Sect E Struct Rep Online

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

Published: August 2008

The title complex, [Cu(2)(C(13)H(18)N(2)O(3))(2)]·C(3)H(6)O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5'-bis-(diethyl-amino)-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenol, where one of the N-O bonds of the ligand was cleaved during the reaction. The complex mol-ecule has a μ-dialkoxo-bridged binuclear structure with both Cu(II) centers exhibiting a square-planar coordination geometry.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960577PMC
http://dx.doi.org/10.1107/S1600536808024707DOI Listing

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