The title compound, [Ni(C(3)H(10)N(2))(3)][Ni(CN)(4)], is built up of [Ni(pn)(3)](2+) cations (pn is 1,2-diamino-propane) and [Ni(CN)(4)](2-) anions. Both Ni(II) atoms in the cation and the anion lie on a mirror plane. The respective ions inter-act through Coulombic forces and through a complex network of hydrogen bonds. Extended disorder associated with the cation has been resolved. The occupancies of the respective disordered positions are 0.4:0.4:0.2.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960350 | PMC |
http://dx.doi.org/10.1107/S1600536807068420 | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!