The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol-ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol-ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu-O distance [2.873 (3) Å] is to a water mol-ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type. O-H⋯O and N-H⋯O hydrogen bonds are observed in the crystal structure.
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http://dx.doi.org/10.1107/S1600536808000160 | DOI Listing |
J Inorg Biochem
December 2024
Department of Molecular and Analytical Chemistry, Interdisciplinary Excellence Centre, University of Szeged, Dóm tér 7-8, H-6720 Szeged, Hungary. Electronic address:
Schiff bases derived from aminoguanidine are extensively investigated for their structural versatility. The tridentate 2-formylpyridine guanylhydrazones act as analogues of 2-formyl or 2-acetylpyridine thiosemicarbazones, where the thioamide unit is replaced by the guanidyl group. Six derivatives of 2-formylpyridine guanylhydrazone were synthesized and their proton dissociation and complex formation processes with Cu(II), Fe(II) and Fe(III) ions were studied using pH-potentiometry, UV-visible, NMR and electron paramagnetic resonance spectroscopic methods.
View Article and Find Full Text PDFSci Total Environ
December 2024
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China. Electronic address:
Biochars prepared at 300-700 °C were functionalized with amidoxime groups to evaluate their selective adsorptive removal capabilities towards Cu(II), Cd(II), and Pb(II). The results show that the amidoxime modification significantly enhanced the the Cu(II) adsorption capacity of the biochar prepared at 300 °C (AOBC300) by 1.6 times, reaching 0.
View Article and Find Full Text PDFChem Biodivers
December 2024
Department of Agricultural, Forestry, Food and Environmental Sciences, University of Basilicata, Potenza, Italy.
New Cd(II), Zn(II), and Cu(II) chelates with cetirizine.2HCl (CETZ.2HCl) in incidence of 1,10 phenanthroline monohydrate (Phen.
View Article and Find Full Text PDFACS Nano
December 2024
Interdisciplinary Materials Research Center, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China.
J Mol Model
November 2024
Department of Physics, Science Faculty, Ege University, Izmir, 35040, Turkey.
Context: In this paper, we present a theoretical study on the complexation of Co(II), Ni(II), and Cu(II) with a pyrazinamide ligand (PZA), which plays an important role in the treatment of tuberculosis and has biological and pharmacological benefits. It is a hybrid organic/inorganic material involving coordination between a metal ion and PZA ligand containing different coordination sites. This allows it to have different binding modes with metal ions and, therefore, provides a versatile ability to coordinate with metals.
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