In the crystal structure of the title compound, C(24)H(23)NO, the phenyl ring makes dihedral angles of 81.53 (11) and 75.35 (12)°, respectively, with the methyl-substituted and the fused benzene rings. The dihedral angle between the two benzene rings is 71.10 (10)°. There is an intra-molecular O-H⋯N hydrogen bond.
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http://dx.doi.org/10.1107/S1600536808030316 | DOI Listing |
Anal Chem
January 2025
Xinjiang Key Laboratory of Trace Chemical Substances Sensing, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi 830000, China.
The specific fluorescent detection of α-methyltryptamine (AMT) presents a great challenge because similar amine groups and benzene rings exist in a variety of amines. Here, we show the precise modulation of the electron-withdrawing strength of the π-conjugate bridge in aldehyde-containing Schiff base-based fluorescent probes for ultratrace AMT discrimination. It is found that different electron-withdrawing groups -CH, -CHN, and -CHBr as the π-conjugate bridge of the 2-dicyanomethylidene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran (TCF)-based probes can classify and identify organic amines with different amine nucleophilicities.
View Article and Find Full Text PDFNat Commun
January 2025
Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering, Zhangjiang Institute for Advanced Study, Shanghai Jiao Tong University, Shanghai, 200240, China.
In drug development, the substitution of benzene rings in aniline-based drug candidates with saturated bridged bicyclic ring systems often enhances pharmacokinetic properties while preserving biological activity. However, current efforts predominantly focuses on bicyclo[1.1.
View Article and Find Full Text PDFSmall
January 2025
Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, School of Chemistry and Materials Science, Jiangsu Normal, University Xuzhou, Jiangsu, 221116, P. R. China.
Fabricating visible-light-responsive metal-organic frameworks (MOFs) with high stability and effective catalytic functionality remains a long-term pursuit yet a great challenge. Herein, a strategy of increasing ligand and cluster connectivity is developed to construct highly stable fluorescein MOFs, La-CFL, presenting a new (4,8)-connected topological structure compared to Cd-FL constructed using 6-connected dinuclear clusters and 3-connected tritopic ligands. La(CFL) containers like Chinese "Ritual Wine Vessels (Jue)" resemble linear arrangements interconnected by the [La(COO)] clusters.
View Article and Find Full Text PDFACS Omega
January 2025
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 50/38 Akademgorodok, Krasnoyarsk 330036, Russia.
The magnetization and anisotropy of magnetic susceptibility of a 5CB nematic liquid crystal doped three extracts containing chlorophylls a and b and carotenoids in different weight percentage has been studied. The extracts have been dissolved in the liquid crystal matrix at a concentration of 2%. The magnetic susceptibility of the substances has been measured by the Faraday-Curie balance method.
View Article and Find Full Text PDFDalton Trans
January 2025
School of Energy Resources, China University of Geosciences (Beijing), Beijing 100083, P.R. China.
Graphdiyne (GDY), which is composed of benzene rings and acetylene linkage units, is a new allotrope of carbon material. In particular, the large triangular pores of GDY, with a diameter of 5.4 Å, theoretically predict a higher lithium embedding density than traditional graphite anodes, making it a promising candidate for energy storage materials in lithium-ion (Li-ion) batteries.
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