AI Article Synopsis

  • The compound [ZnCl(2)(C(11)H(10)N(2))] features a zinc (Zn) atom coordinated in a distorted tetrahedral shape, bonded to two nitrogen (N) atoms from a bipyridine ligand and two chlorine (Cl) atoms.
  • There are notable π-π interactions occurring between the pyridine rings and a five-membered ring, indicating some level of molecular stacking or interaction.
  • The measured distances between the centers of the rings are 3.685 Å and 3.757 Å, suggesting a close proximity that contributes to the stability and properties of the compound.

Article Abstract

In the mol-ecule of the title compound, [ZnCl(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 6-methyl-2,2'-bipyridine ligand and by two Cl atoms. There are π-π contacts between the pyridine ring and the five-membered ring, and also between the pyridine rings, [centroid-centroid distances = 3.685 (3) and 3.757 (3) Å, respectively].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959229PMC
http://dx.doi.org/10.1107/S1600536808028894DOI Listing

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