N'-Ferrocenyl-2-hydroxy-benzohydrazide.

Acta Crystallogr Sect E Struct Rep Online

Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, People's Republic of China.

Published: December 2007

The title complex, [Fe(C(5)H(5))(C(13)H(11)N(2)O(3))], was prepared via self-assembly using ferrocenyl hydrazide and ethyl salicylate. The compound is potentially a tridentate ferrocene-based ligand. The conformation of the mol-ecule allows the formation of an intra-molecular N-H⋯O hydrogen bond involving the hydroxyl group. The CONHNHCO unit and the rings bonded to it are nearly coplanar. The crystal structure is stabilized by inter-molecular O-H⋯O(carbon-yl) and N-H⋯O(carbon-yl) hydrogen bonds.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915112PMC
http://dx.doi.org/10.1107/S1600536807065634DOI Listing

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