The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H⋯O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915101 | PMC |
http://dx.doi.org/10.1107/S1600536807065105 | DOI Listing |
Acta Crystallogr Sect E Struct Rep Online
December 2007
The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt.
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