The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H⋯O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915101PMC
http://dx.doi.org/10.1107/S1600536807065105DOI Listing

Publication Analysis

Top Keywords

{1-[1-3-carboxy-propanamidoeth-yl]-1'2-bis-diphenyl-phosphinoferrocene-κpp'}dichloridoplatinumii dichloro-methane
4
dichloro-methane 125-solvate
4
125-solvate dinuclear
4
dinuclear title
4
title compound
4
compound [feptcl2c17h14pc23h23no3p]·125ch2cl2
4
[feptcl2c17h14pc23h23no3p]·125ch2cl2 distorted
4
distorted cis-ptcl2p2
4
cis-ptcl2p2 square-planar
4
square-planar geometry
4

Similar Publications

The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!