Cyanidophenyl-tris(trimethyl-phosphine)cobalt(II).

Acta Crystallogr Sect E Struct Rep Online

Published: December 2007

The title mol-ecule, [Co(C(6)H(5))(CN)(C(3)H(9)P)(3)], lies on a crystallographic mirror plane with the Co(II) ion coordinated in a distorted square-pyramidal environment with one of the P atoms in the apical position. In the basal plane, the phenyl substituent is trans to the cyanide group with a C-Co-C angle which is significantly distorted from linearity.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915065PMC
http://dx.doi.org/10.1107/S1600536807064781DOI Listing

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