The anion of the title complex, Cs(2)[PuCl(4)O(2)], adopts a pseudo-octa-hedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetra-chlorido-dioxido-plutonate(VI) anion. Principal bond lengths include Pu-O = 1.752 (3) Å and Pu-Cl = 2.6648 (8) Å.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914883 | PMC |
| http://dx.doi.org/10.1107/S1600536807066354 | DOI Listing |
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