Evaluation of polyketones with N-cyclic structure as electrode material for electrochemical energy storage: case of pyromellitic diimide dilithium salt.

Chem Commun (Camb)

Laboratoire de Réactivité et Chimie des Solides, UMR CNRS 6007, Université de Picardie Jules Verne, 33 rue Saint-Leu, 80039 Amiens Cedex, France.

Published: February 2011

Pyromellitic diimide dilithium salt was selected to complete our database on redox-active polyketones with a N-cyclic structure. Although never reported to date, such a lithiated salt was readily synthesized making its electrochemical evaluation in a Li battery possible. Preliminary data show that this novel material reversibly inserts two Li per formula unit at a relatively low potential giving a stable capacity value of 200 mAh g(-1).

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Source
http://dx.doi.org/10.1039/c0cc04440gDOI Listing

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