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Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity. | LitMetric

The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li(4)·3thf}(4)(μ(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li(4) sites has negligible effect on the structural parameters.

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http://dx.doi.org/10.1039/c0cc04483kDOI Listing

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