Electropolymerization of 3,4-(2-benzylpropylene)-dioxythiophene (ProDOT-Bz) on (approximately 7 microm diameter) single carbon fiber microelectrodes (SCFMEs) in different electrolytes resulted the network of nanofiber structure. Electropolymerization performed in different electrolytes by using cyclovoltammetric technique. Surface morphology of coatings was investigated by Scanning Electron Microscopy (SEM), the attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) was used for the characterization. A linear relationship between peak currents of films with polymerization charge, and capacitances and coating thickness were obtained. The size of nanofiber network (and pores) can be controlled by the scan rate of the cyclovoltammetric process. Electrochemical impedance spectroscopic investigation of these nanostructures has been indicated the capacitive behavior of electrode system. Electrochemical Impedance Spectroscopic characterization (Capacitance) of the PProDOTBz/SCFME consisting cell was simulated at applied potential and parameters explained by equivalent circuit modeling.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1166/jnn.2010.2672 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Nano-fibrous biopolymers as building blocks for gel networks: Interactions, characterization, and applications.
Adv Colloid Interface Sci
January 2025
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 1H9, Canada. Electronic address:
Biopolymers derived from natural resources are highly abundant, biodegradable, and biocompatible, making them promising candidates to replace non-renewable fossil fuels and mitigate environmental and health impacts. Nano-fibrous biopolymers possessing advantages of biopolymers entangle with each other through inter-/intra-molecular interactions, serving as ideal building blocks for gel construction. These biopolymer nanofibers often synergize with other nano-building blocks to enhance gels with desirable functions and eco-friendliness across various applications in biomedical, environmental, and energy sectors.
View Article and Find Full Text PDFHighly compressible lamellar graphene/cellulose/sodium alginate aerogel via bidirectional freeze-drying for flexible pressure sensor.
Int J Biol Macromol
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China; College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China. Electronic address:
Graphene exhibits exceptional electrical properties, and aerogels made from it demonstrate high sensitivity when used in sensors. However, traditional graphene aerogels have poor biocompatibility and sustainability, posing potential environmental and health risks. Moreover, the stacking of their internal structures results in low compressive strength and fatigue resistance, which limits their further applications.
View Article and Find Full Text PDFEnhanced electrochemical performance of a polyaniline-based supercapacitor by a bicontinuous microemulsion nanoreactor approach.
RSC Adv
January 2025
Department of Chemical and Materials Engineering, School of Engineering & Digital Science, Nazarbayev University Astana 010000 Kazakhstan
Polyaniline (PANI)-based supercapacitors suffer from environmental and mechanical instabilities. In this work, a novel bicontinuous microemulsion approach was developed to fabricate a unique nanofibre structure of polyaniline and its 3D-crosslinked network using crosslinking chemistry, which improved both the mechanical and electrochemical performance of a PANI-based supercapacitor. The polyaniline nanofibers and its 3D-crosslinked networks produced by bicontinuous nanoreactors were investigated using experimental tools, such as SEM, FTIR, BET, TGA and DSC.
View Article and Find Full Text PDFTungsten Carbide Embedded in a Porous Carbon Nanofiber Sandwich Structure Electrode: A Strategy to Improve the Performance of Lithium-Sulfur Batteries.
Langmuir
January 2025
College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China.
Lithium-sulfur (Li-S) batteries hold significant promise due to high energy density, cost-effectiveness, and ecological sustainability, but their practical applications are constrained by suboptimal electrochemical performance and the detrimental shuttle effect. Herein, a porous, sandwich-structured composite was developed to function as a freestanding cathode designed for Li-S batteries without aluminum foil. Porous carbon nanofibers (PCNF) were employed as the conductive matrix for sulfur, with tungsten carbide (WC) being incorporated to furnish abundant active sites for polysulfide adsorption.
View Article and Find Full Text PDFHierarchical 3D FeCoNi Alloy/CNT @ Carbon Nanofiber Sponges as High-Performance Microwave Absorbers with Infrared Camouflage.
Materials (Basel)
December 2024
Shanghai Frontiers Science Research Center of Advanced Textiles, Engineering Research Center of Technical Textiles (Ministry of Education), Key Laboratory of Textile Science & Technology (Ministry of Education), College of Textiles, Donghua University, Shanghai 201620, China.
Microwave absorbers with infrared camouflage are highly desirable in military fields. Self-supporting 3D architectures with tailorable shapes, composed of FeCoNi alloy/carbon nanotubes (CNTs) @ carbon nanofibers (CNFs), were fabricated in this study. On the one hand, multiple loss mechanisms were introduced into the high-elastic sponges.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!