Indium(I)-catalyzed alkyl-allyl coupling between ethers and an allylborane.

Chem Commun (Camb)

Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Published: January 2011

An efficient method for alkyl-allyl cross-coupling between ethers and a 9-BBN-derived allylborane catalyzed by indium(I) triflate has been developed. The allylborane proved to be essential to obtain the desired products in high yields. The reaction displayed good substrate scope including high functional group tolerance.

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Source
http://dx.doi.org/10.1039/c0cc03673kDOI Listing

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