Silicon, being in the same group in the periodic table as carbon, plays a key role in modern semiconductor industry. However, unlike carbon nanotube (NT), progress remains relatively slow in silicon NT (SiNT) and SiNT-based heteroarchitectures, which would be the fundamental building blocks of various nanoscale circuits, devices, and systems. Here, we report the synthesis of linear and branched crystalline SiNTs via porous anodic aluminum oxide (AAO) self-catalyzed growth and postannealing, and the connection of crystalline SiNTs and gold nanowires (AuNWs) via a combinatorial process of electrodepositing AuNWs with predesired length and location in the channels of the AAO template and subsequent AAO self-catalyzed and postannealing growth of SiNTs in the remaining empty channels adjacent to the AuNWs. Using the approach, a large variety of two-segment AuNW/SiNT and three-segment SiNT/AuNW/SiNT heteronanostructures with both linear and branched topologies have been achieved, paving the way for the rational design and fabrication of SiNT-based nanocircuits, nanodevices, and multifunctional nanosystems in the future.
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