We show, to the best of our knowledge, the first simulation result of the strong plasmonic field coupling and enhancement at the Ag/Si interface of a silver core/protruded silicon shell nanocylinder by using the finite-element method. The strong plasmon field, with a slow effective phase velocity accumulated at the Ag/Si interface, which results from the large effective index of the surface plasmon due to the nearly identical real parts with opposite signs of the permittivities of silver and silicon at 633 nm, is analyzed. When the silicon shell has shallow protrusions of proper periodicity to meet the phase matching condition between the incident light and the surface plasmon wave at the Ag/Si interface, a higher scattered electric field and a higher sensitivity to the refractive index change of the surrounding medium can be achieved. Furthermore, a feasible implementation of the core-shell nanocylinder design concept is studied and discussed.
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http://dx.doi.org/10.1364/AO.49.006295 | DOI Listing |
Angew Chem Int Ed Engl
December 2024
Universität Heidelberg: Universitat Heidelberg, Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, 69120, Heidelberg, GERMANY.
Electromerism (aka. valence tautomerism) corresponds to the switching of electronic distributions between redox-active ligands and central elements. While this phenomenon is well established for several transition metals, the Pd(0)/Pd(II) couple could not yet be involved due to the high energy of the Pd(0) state.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
College of Materials Science & Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing University of Technology, Beijing 100124, China.
Electrochemical carbon dioxide reduction reaction (ECORR) to produce high value-added products is a promising and effective strategy for closing the artificial carbon cycle and achieving sustainable development of resource. However, catalyst structural reorganization and agglomeration caused by the reduction process will reduce the catalytic performance. In this study, a carbon nitrogen shell with cupper-doped (CNCu shell) catalyst was prepared using silicon dioxide (SiO) as a template.
View Article and Find Full Text PDFJ Synchrotron Radiat
January 2025
Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30013, Taiwan.
Coherent diffraction microscopy (CDM) is a robust direct imaging method due to its unique 2D/3D phase retrieval capacity. Nonetheless, its resolution faces limitations due to a diminished signal-to-noise ratio (SNR) in high-frequency regions. Addressing this challenge, X-ray ensemble diffraction microscopy (XEDM) emerges as a viable solution, ensuring an adequate SNR in high-frequency regions and effectively surmounting resolution constraints.
View Article and Find Full Text PDFSmall
December 2024
State Key Laboratory for Mechanical Behavior of Materials, Shaanxi International Research Center for Soft Matter, Xi'an Jiaotong University, Xi'an, 710049, China.
Stabilization of the silicon-based anode in lithium-ion batteries heavily depends on electrolyte engineering. However, despite the effectiveness of localized high-concentration electrolytes in enhancing battery life, most studies have focused on solvents and lithium salts, highlighting the urgent need for advanced diluents tailored to silicon-based anodes. Here, a nonflammable electrolyte with a weakly lithiophilic diluent is reported by introducing methyl perfluorobutyl ether into a mixture of lithium bis(fluorosulfonyl)imide and 1,2-dimethoxyethane, for the enhancement of silicon-based anode.
View Article and Find Full Text PDFMicrosyst Nanoeng
December 2024
Guangdong Key Laboratory of Precision Equipment and Manufacturing Technology, South China University of Technology, Guangzhou, 510641, China.
Wearable electrocardiogram (ECG) devices are the mainstream technology in the diagnosis of various cardiovascular diseases, in which soft, flexible, permeable electrodes are the key link in human-machine interface to capture bioelectrical signals. Herein, we propose a self-template strategy to fabricate silver-coated fiber/silicone (AgCF-S) electrodes. With a simple dissolving-curing-redissolving process, the polyvinyl acetate shell around the AgCF core is in-situ removed to form a three-dimensional (3D) multi-channel structure.
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