A novel, miniaturized, high-efficiency photocatalytic cell, able to work in dynamic conditions, has been designed and validated in this study. Microfluidic channels were molded out of polydimethylsiloxane (PDMS) by means of standard soft lithography techniques, so as to work as photocatalytic cells, where the coupling of anatase titanium dioxide thin films and platinum electrodes, allows an electrically assisted photocatalytic reaction to produce dissolved oxygen gas from the water content of flowing fluid (e.g. blood). The thin films were deposited onto quartz glass substrates at room temperature (300 K) using reactive radio-frequency sputtering with a titanium metal target. The photocatalytic activity was evaluated through reduction rate of methylene blue solution. The results of the current study, as a proof of concept, have shown that the device can generate oxygen at a rate of 4.06 μM O(2)/(cm(2)min), thus extending its possible application range to the full oxygenation of flowing venous blood.
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http://dx.doi.org/10.1016/j.medengphy.2010.10.008 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 8410501, Israel.
Cuprous oxide (CuO) thin films were chemically deposited from a solution onto GaAs(100) and (111) substrates using a simple three-component solution at near-ambient temperatures (10-60 °C). Interestingly, a similar deposition onto various other substrates including Si(100), Si(111), glass, fluorine-doped tin oxide, InP, and quartz resulted in no film formation. Films deposited on both GaAs(100) and (111) were found alongside substantial etching of the substrates.
View Article and Find Full Text PDFEnviron Technol
January 2025
Tekirdağ Metropolitan Municipality, TESKİ, Water and Sewerage Administration, Tekirdağ, Turkey.
This study explores variations in groundwater (GW) pH, conductivity, ammonium, iron, and manganese parameters to reveal prospective interactions having an impact on the dissolved metal concentrations. To this end, bivariate and partial correlation procedures were applied to the data to obtain incisive evaluation. Besides characterisation efforts, photocatalytic iron and manganese removal experiments were also carried out with Ni-doped TiO nano-composite thin films (TFs) on real GW samples.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Materials Science and Engineering, Incheon National University, Incheon 22012, Korea.
HfO-based thin films have garnered significant interest for integrating robust ferroelectricity into next-generation memory and logic chips, owing to their applicability with modern Si device technology. While numerous studies have focused on enhancing ferroelectric properties and understanding their fundamentals, the fabrication of ultrathin HfO-based ferroelectric films has seldom been reported. This study presents the concept of atomic-level stoichiometry control of ferroelectric HfZrO films by examining the molecular-level interactions of precursor molecules in the atomic layer deposition (ALD) process through theoretical calculations.
View Article and Find Full Text PDFNanomicro Lett
January 2025
Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing, 100191, People's Republic of China.
The proliferation of wearable biodevices has boosted the development of soft, innovative, and multifunctional materials for human health monitoring. The integration of wearable sensors with intelligent systems is an overwhelming tendency, providing powerful tools for remote health monitoring and personal health management. Among many candidates, two-dimensional (2D) materials stand out due to several exotic mechanical, electrical, optical, and chemical properties that can be efficiently integrated into atomic-thin films.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Interdisciplinary Material Science Program, Vanderbilt University, Nashville, Tennessee 37235, United States.
Porous silicon (PSi) thin films on silicon substrates have been extensively investigated in the context of biosensing applications, particularly for achieving label-free optical detection of a wide range of analytes. However, mass transport challenges have made it difficult for these biosensors to achieve rapid response times and low detection limits. In this work, we introduce an approach for improving the efficiency of molecule transport in PSi by using open-ended PSi membranes atop paper substrates in a flow-through sensor scheme.
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