Photocatalytic degradation of chemical pollutants in water was investigated using semiconductor oxide catalysts, zinc oxide (ZnO) and titanium dioxide (TiO2) and phenol as the substrate. Influence of various parameters such as characteristics of the catalyst, irradiation time, substrate and catalyst concentrations, pH etc. has been studied and optimum conditions for the complete degradation of phenol in water have been identified. In terms of activity and durability TiO2 is far superior to ZnO. Mixing ZnO with TiO2 does not affect its activity significantly. The process is especially relevant in view of its potential for the treatment of wastewater containing pollutants, using solar radiation as the energy source.
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Environ Sci Pollut Res Int
January 2025
School of Engineering, Macquarie University, Sydney, NSW, 2109, Australia.
This study focuses on the simulation of a solar photocatalytic reactor with linear parabolic reflectors and continuous fluid flow. The simulation approach was initially validated against experimental data reported by Miranda-Garcia et al. Catal Today 151:107-113 (2010), yielding a high degree of accuracy of approximately 0.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
School of Environmental and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China. Electronic address:
Carbon dots (CDs) mediated g-CN (CN) is a promising visible-light-driven semiconductor in catalyzing peroxymonosulfate (PMS) for aqueous contaminants remediation. However, the poor dispersibility of powered catalyst and its challenging recyclability impede their broader application. Herein, we embedded FeN bridge within the g-CN framework and immobilized g-CN gel beads (CA/FNCCN) through a 3D cross-linking process with sodium alginate.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemistry, Career Point University, Hamirpur Campus, H.P., India; CNST, Career Point University, Hamirpur Campus, H.P., India. Electronic address:
In our study, we have tried to enhance the biological qualities of nickel oxide nanoparticles and nanocomposites which were prepared using the extract of Aegle marmelos tree leaves and chitosan biopolymer. For in-depth study of the fabricated samples, numerous physiochemical approaches were utilized. The analysis used consists of field emission scanning electron microscopy with energy dispersive X-ray analysis and photoluminescence, X-ray diffraction, UV-visible spectroscopy, and Fourier transform infrared spectroscopy.
View Article and Find Full Text PDFEnviron Res
January 2025
College of Civil Engineering, Hefei University of Technology, Hefei, 238000, China; Chinaland Solar Energy Co., Ltd., Hefei, 238000, China. Electronic address:
The preparation strategy is the important factor to obtain the effective photocatalyst, and the thermal decomposition could be used to prepare photocatalysts with high crystallinity and photoactivity. In this paper, thermal decomposition method was used to deposit CuO nanoparticles on TiO nanotube arrays (TiO NTs), and the TiO NTs/CuO exhibited remarkably high visible light absorption and photoelectrocatalytic performances toward dye degradation and Cr(VI) reduction. The potential degradation pathway and toxicities of rhodamine B (RhB) dyes and intermediates were investigated.
View Article and Find Full Text PDFSmall
January 2025
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai, 201418, China.
How to improve the stability and activity of metal-organic frameworks is an attractive but challenging task in energy conversion and pollutant degradation of metal-organic framework materials. In this paper, a facile method is developed by fabricating titanium dioxide nanoparticles (TiO NPs) layer on 2D copper tetracarboxylphenyl-metalloporphyrin metal-organic frameworks with zinc ions as the linkers (ZnTCuMT-X, "Zn" represented zinc ions as the linkers, the first "T" represented tetracarboxylphenyl-metalloporphyrin (TCPP), "Cu" represented the Cu coordinated into the porphyrin macrocycle, "M" represented metal-organic frameworks, the second "T" represented TiO NPs layer, and "X" represented the added volume of n-tetrabutyl titanate (X = 100, 200, 300 or 400)). It is found that the optimized ZnTCuMT-200 showed greatly and stably enhanced H generation, which is ≈28.
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