Large arrays of uniform, precisely tunable, open-access optical microcavities with mode volumes as small as 2.2 μm(3) are reported. The cavities show clear Hermite-Gauss mode structure and display finesses up to 460, in addition to quality (Q) factors in excess of 10,000. The cavities are attractive for use in quantum optics applications, such as single atom detection and efficient single photon sources, and have potential to be extended for experiments in the strong coupling regime.
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http://dx.doi.org/10.1364/OL.35.003556 | DOI Listing |
Adv Mater
December 2023
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, School of Materials Science and Engineering, Hebei University of Technology, Tianjin, 300130, China.
The electrodeless biocompatible manipulation of femtoliter-scale aqueous microdroplets remains challenging. The appropriate isolation of electrostatic charges from femtoliter-scale aqueous microdroplets is crucial for electrodeless optoelectronic manipulation based on space-charge-density modulation. Here, surfactant-mediated photovoltaic manipulation is proposed, where the surfactant layers self-assembled at the water-oil and oil-Lithium niobate interfaces are employed to isolate photovoltaic charges.
View Article and Find Full Text PDFAcc Chem Res
May 2023
Department of Chemistry, Purdue University, West Lafayette, Indiana 47906, United States.
ConspectusNanoparticles have witnessed immense development in the past several decades due to their intriguing physicochemical properties. The modern chemist is interested not only in methods of synthesizing nanoparticles with tunable properties but also in the chemistry that nanoparticles can drive. While several methods exist to synthesize nanoparticles, it is often advantageous to put nanoparticles on a variety of conductive substrates for multiple applications (such as energy storage and conversion).
View Article and Find Full Text PDFAnal Chem
July 2020
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States.
Physicochemical analysis of individual atmospheric aerosols at the most abundant sizes in the atmosphere (<1 μm) is analytically challenging, as hundreds to thousands of species are often present in femtoliter volumes. Vibrational spectroscopies, such as infrared (IR) and Raman, have great potential for probing functional groups in single particles at ambient pressure and temperature. However, the diffraction limit of IR radiation limits traditional IR microscopy to particles > ∼10 μm, which have less relevance to aerosol health and climate impacts.
View Article and Find Full Text PDFSmall
January 2019
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, T6G 1H9, Canada.
A universal femtoliter surface droplet-based platform for direct quantification of trace of hydrophobic compounds in aqueous solutions is presented. Formation and functionalization of femtoliter droplets, concentrating the analyte in the solution, are integrated into a simple fluidic chamber, taking advantage of the long-term stability, large surface-to-volume ratio, and tunable chemical composition of these droplets. In situ quantification of the extracted analytes is achieved by surface-enhanced Raman scattering (SERS) spectroscopy by nanoparticles on the functionalized droplets.
View Article and Find Full Text PDFLab Chip
September 2018
Dept. of research & development, SELMA Diagnostics ApS, Copenhagen Bio-Science Park, 2200 Copenhagen, Denmark.
Here we present a water-in-air droplet platform for micro-compartmentalization for single molecule guided synthesis and analysis consisting of a flow-system hosting dense arrays of aqueous microdroplets on a glass surface surrounded by air. The droplets are formed in a few seconds by passing a waterfront over the array of hydrophilic spots surrounded by a hydrophobic coating, thus forming a micro-droplet array (MDA). The droplet volumes are tunable from approximately 50 femtoliter to 20 picoliter by adjusting the size of the hydrophilic spots.
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