Shape controlled synthesis of palladium nanocrystals by combination of oleylamine and alkylammonium alkylcarbamate and their catalytic activity.

Chem Commun (Camb)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, P. R. China.

Published: December 2010

The shape of Pd nanocrystals (NCs) can be controlled by combination of oleylamine (OAm) and alkylammonium alkylcarbamate (AAAC), and Pd spheres, tetrahedra and multipods have been synthesized. The multipods and tetrahedra are much more active than the spheres for hydrogenation reactions.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c0cc03485aDOI Listing

Publication Analysis

Top Keywords

combination oleylamine
8
alkylammonium alkylcarbamate
8
shape controlled
4
controlled synthesis
4
synthesis palladium
4
palladium nanocrystals
4
nanocrystals combination
4
oleylamine alkylammonium
4
alkylcarbamate catalytic
4
catalytic activity
4

Similar Publications

Knowledge of the structure-property relationships of functional nanomaterials, including, for example, their size- and composition-dependent photoluminescence (PL) and particle-to-particle variations, is crucial for their design and reproducibility. Herein, the Angstrom-resolution capability of an analytical ultracentrifuge combined with an in-line multiwavelength emission detection system (MWE-AUC) for measuring the sedimentation coefficient-resolved spectrally corrected PL spectra of dispersed nanoparticles is demonstrated. The capabilities of this technique are shown for giant-shell CdSe/CdS quantum dots (g-QDs) with a PL quantum yield (PL QY) close to unity capped with oleic acid and oleylamine ligands.

View Article and Find Full Text PDF
Article Synopsis
  • Understanding the reaction mechanism and coordination of ligands and solvents is essential for controlling the fabrication of transition metal sulfide nanocrystals.
  • The study employs advanced techniques such as HERFD-XAS and vtc-XES alongside DFT calculations to explore the formation of various zinc complexes during the synthesis of ZnS nanorods in oleylamine.
  • The transition in the electronic structure of the zinc complexes is observed, revealing insights into the size-dependent electronic band gaps of synthesized nanocrystals.
View Article and Find Full Text PDF
Article Synopsis
  • CuZnSnS (CZTS) is a non-toxic semiconductor ideal for solar energy and catalysis applications, synthesized here using a cost-effective method involving copper and zinc acetates with tin chloride and sulfur.
  • The synthesis involved a hot-injection technique that influenced the size and structure of CZTS nanoparticles, with further purification carried out using HCl to eliminate harmful phases.
  • Various analytical techniques, including Raman spectroscopy and X-ray diffraction, confirmed that HCl effectively removed impurities while maintaining the integrity of the nanoparticles.
View Article and Find Full Text PDF
Article Synopsis
  • A new one-pot heating technique was developed to create core/crown SnSe/SnS nanosheets by adjusting the reactivity of sulfur and selenium precursors.
  • The synthesis involves using SnCl and selenium phosphines to form SnSe nanosheets, with the addition of a reactive S-oleylamine complex to grow SnS crowns.
  • Various microscopy methods confirmed the high crystallinity and structure of the resulting core/crown nanosheets.
View Article and Find Full Text PDF
Article Synopsis
  • - The study investigates a new protein, rEnd2, from a bacteriophage that targets and degrades the protective outer layer of bacteria, particularly focusing on its interaction with the antibiotic colistin and its effectiveness when paired with nanoparticles.
  • - The purification and analysis of rEnd2 showed it works best in neutral pH and warm temperatures, with a structural similarity to other known antibacterial proteins, but it loses effectiveness in the presence of certain surfactants.
  • - Despite demonstrating some ability to break down bacterial structure, rEnd2 was not effective enough on its own or even when combined with colistin, indicating the need for further research to improve its antimicrobial capabilities.
View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!