The shape of Pd nanocrystals (NCs) can be controlled by combination of oleylamine (OAm) and alkylammonium alkylcarbamate (AAAC), and Pd spheres, tetrahedra and multipods have been synthesized. The multipods and tetrahedra are much more active than the spheres for hydrogenation reactions.
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http://dx.doi.org/10.1039/c0cc03485a | DOI Listing |
Small Methods
January 2025
Institute of Particle Technology (LFG), Department of Chemical and Biological, Engineering (CBI), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Cauerstraße 4, 91058, Erlangen, Germany.
Knowledge of the structure-property relationships of functional nanomaterials, including, for example, their size- and composition-dependent photoluminescence (PL) and particle-to-particle variations, is crucial for their design and reproducibility. Herein, the Angstrom-resolution capability of an analytical ultracentrifuge combined with an in-line multiwavelength emission detection system (MWE-AUC) for measuring the sedimentation coefficient-resolved spectrally corrected PL spectra of dispersed nanoparticles is demonstrated. The capabilities of this technique are shown for giant-shell CdSe/CdS quantum dots (g-QDs) with a PL quantum yield (PL QY) close to unity capped with oleic acid and oleylamine ligands.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Institute for Nanostructure and Solid-State Physics, Center for Hybrid Nanostructures, University of Hamburg, Luruper Chaussee 149, Hamburg 22761, Germany.
Nanoscale Adv
December 2024
Department of Materials Science and Solar Energy Research Center (MIB-SOLAR), University of Milano-Bicocca Via Cozzi 55 I-20125 Milan Italy
Nano Lett
October 2024
University of Hamburg, Institute of Physical Chemistry, Grindelallee 117, 20146 Hamburg, Germany.
Probiotics Antimicrob Proteins
October 2024
Department of Restorative Dentistry, Ribeirão Preto School of Dentistry, University of São Paulo, Ribeirão Preto, SP, Brazil.
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