OXIDATION OF THIOLS USING K(2)S(2)O(8) IN IONIC LIQUID.

Phosphorus Sulfur Silicon Relat Elem

Dept. of Pharmacology, University of Wisconsin, Medical School, 1300 University Avenue, Madison, 53706-1532, WI, USA.

Published: July 2009

A green, straightforward and novel method for oxidation of thiols to the corresponding disulfides is reported using K(2)S(2)O(8) in the ionic liquid 1-butyl-3-methylimidazolium bromide [(bmim)Br] at 65-70 °C. The corresponding disulfides were obtained in excellent yield and short reaction time.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2958088PMC
http://dx.doi.org/10.1080/10426500802417000DOI Listing

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