The results of a theoretical investigation on the complex cascade reaction leading to the natural product rubicordifolin are reported. These computations analyze the discrete transformations that are required during the conversion of the vinyl naphthoquinone starting material into the natural product, including two pseudopericyclic cyclizations as well as a diastereoselective, hetero-Diels-Alder reaction.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ol102157d | DOI Listing |
Publication Analysis
Top Keywords
theoretical investigation
8
natural product
8
investigation rubicordifolin
4
rubicordifolin cascade
4
cascade theoretical
4
investigation complex
4
complex cascade
4
cascade reaction
4
reaction leading
4
leading natural
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!