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An unusual 3D entangled Co(II) coordination polymer directed by ferromagnetic molecular building block. | LitMetric

An unusual 3D entangled Co(II) coordination polymer directed by ferromagnetic molecular building block.

Inorg Chem

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China.

Published: November 2010

AI Article Synopsis

Article Abstract

A fascinating 3D entangled metal-organic framework, namely, {[Co(2)(bcp)(2)]·3H(2)O}(n) (1), was obtained through the solvothermal generation of flexible and long dicarboxylate (bcp) and metal salt. The crystal structure contains a 1D metal chain with bcp ligands wrapped around it in a wavy line and features an unusual entangled topological net. Furthermore, the magnetic behavior of 1 was also studied and indicated the existence of ferromagnetic interaction and long-range ordering character.

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Source
http://dx.doi.org/10.1021/ic101286jDOI Listing

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