AI Article Synopsis
- An electrode system was created with ferrocene molecules embedded in a hybrid bilayer membrane (HBM) for characterization.
- The redox properties of ferrocene were analyzed by changing the lipid and alkanethiol components of the HBM, revealing that their performance relied on the electrolyte's hydrophobicity and the positioning of ferrocene within the membrane.
- The study also assessed how effectively lipid-embedded ferrocenium ions could oxidize ascorbic acid in solution, finding this ability varied based on the counterion used.
Article Abstract
An electrode-supported system in which ferrocene molecules are embedded in a hybrid bilayer membrane (HBM) has been prepared and characterized. The redox properties of the ferrocene molecules were studied by varying the lipid and alkanethiol building blocks of the HBM. The midpoint potential and electron transfer rate of the embedded ferrocene were found to be dependent on the hydrophobic nature of the electrolyte and the distance at which the ferrocene was positioned in the HBM relative to the electrode and the solution. Additionally, the ability of the lipid-embedded ferrocenium ions to oxidize solution phase ascorbic acid was evaluated and found to be dependent on the nature of the counterion.
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| http://dx.doi.org/10.1021/la1029118 | DOI Listing |
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