The title compound, [(Z)-4-allyl-2-(2-hydroxybenzylidene)thiosemicarbazide-κS][(E)-4-allyl-1-(2-oxidobenzylidene)thiosemicarbazidato-κ(3)O,N(1),S]copper(II) monohydrate, [Cu(C(11)H(11)N(3)OS)(C(11)H(13)N(3)OS)]·H(2)O, crystallized as a rotational twin in the monoclinic crystal system (space group Cc) with two formula unit (Z' = 2) in the asymmetric unit, one of which contains an allyl substituent disordered over two positions. The Cu(II) atom exhibits a distorted square-planar geometry involving two differently coordinated thiosemicarbazone ligands. One ligand is bonded to the Cu(II) atom in a tridentate manner via the phenolate O, azomethine N and thioamide S atoms, while the other coordinates in a monodentate manner via the S atom only. The complex is stabilized by an intramolecular hydrogen bond, which creates a six-membered pseudo-chelate metalla-ring. The structure analysis indicates the presence of the E isomer for the tridentate ligand and the Z isomer for the monodentate ligand. The crystal structure contains a three-dimensional network built from intermolecular O-H...O, N-H...O, O-H...N and N-H...S hydrogen bonds.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1107/S0108270110035754 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Subsets of extraocular motoneurons produce kinematically distinct saccades during hunting and exploration.
Curr Biol
January 2025
Department of Neuroscience, Physiology & Pharmacology, UCL, Gower Street, London WC1E 6BT, UK. Electronic address:
Animals construct diverse behavioral repertoires by moving a limited number of body parts with varied kinematics and patterns of coordination. There is evidence that distinct movements can be generated by changes in activity dynamics within a common pool of motoneurons or by selectively engaging specific subsets of motoneurons in a task-dependent manner. However, in most cases, we have an incomplete understanding of the patterns of motoneuron activity that generate distinct actions and of how upstream premotor circuits select and assemble such motor programs.
View Article and Find Full Text PDFLongitudinal single-cell profiles of lung regeneration after viral infection reveal persistent injury-associated cell states.
Cell Stem Cell
January 2025
Department of Medicine, Perelman School of Medicine, University of Pennsylvania, Philadelphia, PA 19104, USA; Department of Cell and Developmental Biology, University of Pennsylvania, Philadelphia, PA 19104, USA; Penn-Children's Hospital of Philadelphia Lung Biology Institute, University of Pennsylvania, Philadelphia, PA 19104, USA; Penn Cardiovascular Institute, University of Pennsylvania, Philadelphia, PA 19104, USA. Electronic address:
Functional regeneration of the lung's gas exchange surface following injury requires the coordination of a complex series of cell behaviors within the alveolar niche. Using single-cell transcriptomics combined with lineage tracing of proliferating progenitors, we examined mouse lung regeneration after influenza injury, demonstrating an asynchronously phased response across different cellular compartments. This longitudinal atlas of injury responses has produced a catalog of transient and persistent transcriptional alterations in cells as they transit across axes of differentiation.
View Article and Find Full Text PDFTransplant 101: Helping Patients Navigate the Complexity of the Kidney Transplant Waitlist.
Nephrol Nurs J
January 2025
Kidney Transplant Coordinator, Atrium Health, Carolinas Medical Center in Charlotte, NC.
Patients in need of a kidney transplant have the option of receiving a kidney from a living donor or a deceased donor. Patients in the United States who do not have an available living donor typically wait on the deceased donor waiting list for an average of three to five years, although some patients may wait longer. The waiting list is very complex and intended to allocate kidneys in a fair and equitable manner.
View Article and Find Full Text PDFA unified approach to SimpleTreat input and settings for wastewater treatment removal predictions.
Integr Environ Assess Manag
January 2025
European Centre for Ecotoxicology and Toxicology of Chemicals, Brussels, Belgium.
SimpleTreat has become a common tool used in ecological risk assessments to estimate the removal efficiency of a chemical from a secondary wastewater treatment plant and hence inform on release to the environment. Organization A, Organization B, and Organization C performed a comparative study of SimpleTreat predictions and parameter selection methodologies across the three organizations. SimpleTreat versions 3.
View Article and Find Full Text PDFKinetic Separation of Butane Isomers Using a Formate Metal-Organic Framework.
Chempluschem
January 2025
Sun Yat-Sen University, School of Chemistry, CHINA.
n-butane (n-C4H10) and isobutane (i-C4H10) are important raw materials in chemical industry. The separation of the two hydrocarbon isomers via distillation is challenging and energy-consuming. Herein we report the adsorption behavior of a microporous cobalt formate framework [Co3(HCOO)6] for potential kinetic separation of butane isomers.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!