Revealing the exciton fine structure of PbSe nanocrystal quantum dots using optical spectroscopy in high magnetic fields.

Phys Rev Lett

Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.

Published: August 2010

We measure the photoluminescence lifetime τ of excitons in colloidal PbSe nanocrystals (NCs) at low temperatures to 270 mK and in high magnetic fields to 15 T. For all NCs, τ increases sharply below 10 K but saturates by 500 mK. In contrast to the usual picture of well-separated "bright" and "dark" exciton states (found, e.g., in CdSe NCs), these dynamics fit remarkably well to a system having two exciton states with comparable--but small--oscillator strengths that are separated by only 300-900  μeV depending on NC size. Importantly, magnetic fields reduce τ below 10 K, consistent with field-induced mixing between the two states. Magnetic-circular dichroism studies reveal exciton g factors from 2-5, and magnetophotoluminescence shows >10% circularly polarized emission.

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http://dx.doi.org/10.1103/PhysRevLett.105.067403DOI Listing

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