We show that the chirality of triangular antiferromagnetic clusters can be used as a qubit even if it is entirely decoupled from the total spin of the cluster. In particular, we estimate the orbital moment associated with the chirality, and we show that it can be large enough to allow a direct measurement of the chirality with a field perpendicular to the cluster. Consequences for molecular magnets are discussed, and an alternative implementation with Cu atoms on a surface is proposed, for which one- and two-qubit gates are worked out in detail. Decoherence effects are also discussed.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.104.200502 | DOI Listing |
Sci Rep
January 2025
Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznan, 61 614, Poland.
The embellishing of the macrocycle core with sulfur substituents of varied sterical requirements changes the structural dynamics of chiral, triangular polyimines. Despite their formal high symmetry, these compounds adopt diverse conformations, in which the macrocycle core represents a non-changeable unit. DFT calculations reveal that the mutual arrangement of sulfur-containing substituents is controlled mainly by sterical interactions.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, China.
Nat Commun
January 2025
Empa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland.
Studying the self-assembly of chiral molecules in two dimensions offers insights into the fundamentals of crystallization. Using scanning tunneling microscopy, we examine an uncommon aggregation of polyaromatic chiral molecules on a silver surface. Dense packing is achieved through a chiral triangular tiling of triads, with N and N ± 1 molecules at the edges.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Beijing National Laboratory of Molecular Sciences and CAS Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, North First Street 2, Zhongguancun, Beijing, 100190, China.
Here, we report the synthesis and self-assembly of a novel chiral 2,3 : 6,7-naphthalenediimide-based triangular macrocycle (NDI-Δ) and its chiroptical properties. The enantiomeric NDI-Δ is synthesized by condensation of (RR) or (SS)-trans-1,2-cyclohexanediamine and 2,3,6,7-naphthalenetetracarboxylic 2,3 : 6,7-dianhydride, in which the chirality of the macrocycles is controlled by the diamine. With the rigid outer π-surface, the macrocycle exhibits unique chiroptical properties and self-assembly modes.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
College of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, China.
- exhibited significant aggregation-induced Emission (AIE) characteristics, including high brightness (αAIE ≈ 40), robust light stability, a substantial Stokes shift (128 nm), and a high signal-to-noise ratio, effectively overcoming aggregation-caused quenching (ACQ). Derived from the axially chiral -H-BINOL, - was synthesized via nucleophilic cyclization and exhibited pronounced self-assembly properties. Through robust intra- and intermolecular hydrogen bonding interactions, - formed diverse supramolecular structures, including spherical flower-like aggregates, hollow-core triangular tubules, hexagonal tubules, and irregular white block-like stacks.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!