We analyze the irreversibility and the entropy production in nonequilibrium interacting particle systems described by a Fokker-Planck equation by the use of a suitable master equation representation. The irreversible character is provided either by nonconservative forces or by the contact with heat baths at distinct temperatures. The expression for the entropy production is deduced from a general definition, which is related to the probability of a trajectory in phase space and its time reversal, that makes no reference a priori to the dissipated power. Our formalism is applied to calculate the heat conductance in a simple system consisting of two Brownian particles each one in contact to a heat reservoir. We show also the connection between the definition of entropy production rate and the Jarzynski equality.
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http://dx.doi.org/10.1103/PhysRevE.82.021120 | DOI Listing |
Appl Biochem Biotechnol
January 2025
Department of Botany, Maharshi Dayanand University, Rohtak, 124001, India.
Cellulase was effectively immobilized onto an epoxy-bound chitosan-modified zinc metal-organic framework (epoxy/ZIF-8/CS/cellulase) support, yielding a conjugation rate of 0.64 ± 0.02 mg/cm2 and retaining 80.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Optoelectronic Technology, Fuzhou University, Fuzhou 350116, China.
Anticounterfeiting technologies meet challenges in the Internet of Things era due to the rapidly growing volume of objects, their frequent connection with humans, and the accelerated advance of counterfeiting/cracking techniques. Here, we, inspired by biological fingerprints, present a simple anticounterfeiting system based on perovskite quantum dot (PQD) fingerprint physical unclonable function (FPUF) by cooperatively utilizing the spontaneous-phase separation of polymers and selective in situ synthesis PQDs as an entropy source. The FPUFs offer red, green, and blue full-color fingerprint identifiers and random three-dimensional (3D) morphology, which extends binary to multivalued encoding by tuning the perovskite and polymer components, enabling a high encoding capacity (about 10, far surpassing that of biometric fingerprints).
View Article and Find Full Text PDFPLoS One
January 2025
School of Finance, Harbin University of Commerce, Harbin, China.
Environmental pollution has become a global concern, so it is critical to find out the elements that influence it. Is the urban business credit environment influencing urban environmental conditions? The study takes the entropy method for calculating the environmental pollution index of 276 prefecture-level cities across China from 2010 to 2021, the CE1 index to describe the urban business credit environment, and a spatial Durbin model to empirically analyze the mechanism and transmission path of the urban business credit environment on environmental pollution. The findings demonstrate that: (1) there is an important positive spatial association between China's urban pollution index and urban business credit index, and that the level of spatial clustering of the two is increasing over time.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Department of Chemistry, National Institute of Technology Nagaland, Chumukedima, Nagaland 797103, India.
As one of nature's most fundamental blueprints and due to its critical role in life processes, DNA has naturally become the cornerstone of numerous research efforts. One particularly intriguing area of study is understanding how small molecules interact with nucleic acids. In this study, we investigated the interaction between the plant-derived indole alkaloid Raubasine (Ajmalicine; AJM) and Salmon Testes (ST) DNA using biophysical and computational techniques.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Department of Mathematics and Physics Engineering, Faculty of Engineering, Mansoura University, El-Mansoura 35516, Egypt.
Bimetallic NiCr nanoparticles decorated on carbon nanofibers (NiCr@CNFs) were synthesized through electrospinning and investigated as catalysts for hydrogen generation from the dehydrogenation of sodium borohydride (SBH). Four distinct compositions were prepared, with chromium content in the catalysts ranging from 5 to 25 weight percentage (wt%). Comprehensive characterization confirmed the successful formation of bimetallic NiCr@CNFs.
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