We report electric field dependence of the anchoring transition in a mesogen on cooling in a cell with perfluoropolymer treated surfaces. Below a crossover voltage V(co) the transition is discontinuous between planar and homeotropic alignments, and as the temperature is lowered, the transition temperature decreases quadratically with the field. Above V(co) the transition is continuous between planar and tilted alignments, the transition temperature decreasing essentially linearly with the rms field. We develop a simple model to account for these results and argue that the higher field regime corresponds to a temperature driven inverse Freedericksz transition in which the director orientation starts tilting at the weakly anchored surfaces while the tilt angle remains zero at the midplane of the cell.
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http://dx.doi.org/10.1103/PhysRevE.82.011701 | DOI Listing |
Phys Rev E
August 2023
Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.
We study the director configurations of nematic liquid crystal (NLC) droplets with homeotropic anchoring in a magnetic field and report observation of a magnetic-field-driven transition from a deformed radial to an axial-with-defect configuration. Magnetic-field-induced transitions in NLC droplets differ fundamentally from the traditional planar Freedericksz transition due to the spherical droplet geometry and resulting topological defect. This transition has been studied theoretically, but the director configurations and mechanism of defect evolution in an applied magnetic field have yet to be observed experimentally.
View Article and Find Full Text PDFJ Phys Chem B
July 2016
Faculty of Science, University of Paderborn, Warburger Str. 100, 33098 Paderborn, Germany.
Pattern formation in binary calamitic liquid crystal mixtures with positive dielectric anisotropy and negative conductivity anisotropy, which attracted attention owing to field-induced light scattering under unusual conditions many years ago, is reinvestigated in the conductive regime. Homeotropic cells with these mixtures exhibit a direct transition to isotropic electroconvection, while planar cells show a Fréedericksz transition to the quasi-homeotropic state and subsequent electroconvection at higher voltages. A temperature-induced change from normal and oblique convection rolls to longitudinal rolls reveals a transition from standard electroconvection to nonstandard electroconvection, which can be attributed to a sign inversion of the conductivity anisotropy.
View Article and Find Full Text PDFEur Phys J E Soft Matter
December 2012
CNISM and Dipartimento di Fisica, Università di Siena, Italy.
Phys Rev E Stat Nonlin Soft Matter Phys
July 2010
School of Physics, University of Hyderabad, Hyderabad 500046, India.
We report electric field dependence of the anchoring transition in a mesogen on cooling in a cell with perfluoropolymer treated surfaces. Below a crossover voltage V(co) the transition is discontinuous between planar and homeotropic alignments, and as the temperature is lowered, the transition temperature decreases quadratically with the field. Above V(co) the transition is continuous between planar and tilted alignments, the transition temperature decreasing essentially linearly with the rms field.
View Article and Find Full Text PDFPhys Rev E Stat Nonlin Soft Matter Phys
September 2003
Physics and Mathematical Sciences, The Nottingham Trent University, Clifton Lane, Nottingham NG11 8NS, United Kingdom.
Continuum theory is used to demonstrate that the presence of flexoelectricity significantly alters the response to an applied voltage of a homogeneous nematic liquid crystal cell above the ac Fréedericksz threshold voltage. In such a system there is a fitting degeneracy: we obtain very good fits between theory and experimental permittivity data using any value of the sum of flexoelectric coefficients, e(11)+e(33), between 0.0 C/m and 1.
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