AI Article Synopsis
- The irradiation of chromone-2-carboxylic esters leads to the selective creation of C(2) chiral anti-HH dimers when exposed to light in the triplet excited state.
- When the same compounds are exposed to light in solid-state conditions, they produce anti-HT dimers.
- The formation of these dimers in solid-state is influenced by the arrangement of molecules within the crystal structure.
Article Abstract
The irradiation of chromone-2-carboxylic esters resulted in the stereo- and regioselective formation of C(2) chiral anti-HH dimers from the triplet excited state. On the contrary, photolysis in the solid-state gave anti-HT dimers exclusively controlled by molecular arrangement in the crystal.
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| http://dx.doi.org/10.1021/ol101734k | DOI Listing |
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