Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.

J Am Chem Soc

Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Published: October 2010

The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in good to excellent yields.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2975586PMC
http://dx.doi.org/10.1021/ja107481aDOI Listing

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