A spatially modulated laser is used to produce multiple localized thermal gradients in a colloidal sample placed above a gold surface. We use an optical microscope to observe real time dynamics of the resulting two-dimensional colloidal crystal grains and find that grain rotation-induced grain coalescence (GRIGC) occurs with the rotation of both grains before coalescence. Control over the grain size shows that the time scale for grain boundary annealing in our system is in good agreement with theoretical expressions formulated for nanocrystal growth.
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http://dx.doi.org/10.1021/nl102786k | DOI Listing |
ACS Nano
May 2021
Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.
Understanding the bottom-up synthesis of atomically thin two-dimensional (2D) crystals and heterostructures is important for the development of new processing strategies to assemble 2D heterostructures with desired functional properties. Here, we utilize laser-heating within a transmission electron microscope (TEM) to understand the stages of crystallization and coalescence of amorphous precursors deposited by pulsed laser deposition (PLD) as they are guided by 2D crystalline substrates into van der Waals (vdW) epitaxial heterostructures. Amorphous clusters of tungsten selenide were deposited by PLD at room temperature onto graphene or MoSe monolayer crystals that were suspended on TEM grids.
View Article and Find Full Text PDFRSC Adv
May 2019
School of Materials Science and Engineering, Central South University Changsha 410083 China.
In order to address the issue of metal ion incorporation during polymerization, citric acid was used as a chelating agent to improve the polyacrylamide gel route. In the present work, MgO nanoparticles were synthesized this improved method. The calcination temperature of the gel precursor containing magnesium nitrate was determined by thermogravimetry and differential scanning calorimetry (TG-DSC).
View Article and Find Full Text PDFAstrophys J
June 2016
NASA Ames Research Center, MS-245-3, Moffett Field, CA 94035, U.S.A.
Many of the directly imaged self-luminous gas giant exoplanets have been found to have cloudy atmospheres. Scattering of the emergent thermal radiation from these planets by the dust grains in their atmospheres should locally give rise to significant linear polarization of the emitted radiation. However, the observable disk averaged polarization should be zero if the planet is spherically symmetric.
View Article and Find Full Text PDFACS Nano
December 2013
Department of Materials Science and Engineering and ‡Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.
Spherical nucleic acid (SNA) nanostructures assemble into a large variety of well-defined crystalline superlattices via DNA-directed hybridization. Crystallities of SNA with various shapes emerge during the assembly process, which coalesce during coarsening, leading to polycrystalline materials. Here, we investigate the growth dynamics of SNAs into body-centered cubic superlattices and the coalescence of SNA aggregates using a colloidal model formulated from the competition of electrostatic core repulsions and localized DNA hybridization attractions.
View Article and Find Full Text PDFPhys Rev E Stat Nonlin Soft Matter Phys
August 2013
Niels Bohr Institute, University of Copenhagen, Blegdamsvej 17, DK-2100 Copenhagen, Denmark.
We consider grain growth and stagnation in polycrystalline microstructures. From the phase-field crystal modeling of the coarsening dynamics, we identify a transition from a grain-growth stagnation upon deep quenching below the melting temperature T(m) to a continuous coarsening at shallower quenching near T(m). The grain evolution is mediated by local grain rotations.
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