Dynamic changes in dimensional structures of co-complex crystals.

Inorg Chem

Collaborative Innovation Center for Nanotech FIBER (nanoFIC), Shinshu University, Ueda Nagano 386-8567, Japan.

Published: October 2010

AI Article Synopsis

  • A 2D flexible porous coordination polymer (2D-PCP) was created by manipulating its dimensionality from zero-dimensional and one-dimensional polymers.
  • This 2D-PCP undergoes expansion and shrinkage, showcasing significant structural changes and the ability to accommodate different molecules.
  • The study included an examination of the kinetics involved in these structural transformations, highlighting the cooperative dynamic processes that occur in the solid state.

Article Abstract

A two-dimensional flexible porous coordination polymer (2D-PCP) that shows expansion/shrinkage structural transformation accompanied by molecular accommodation was synthesized by control of dimensionality in zero-dimensional and one-dimensional PCPs: The dynamic structural transformation cooperatively proceeds in the solid state with a drastic molecular rearrangement. Kinetics of the structural transformation was investigated.

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http://dx.doi.org/10.1021/ic100753gDOI Listing

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