A photoreactive crystalline quasiracemate.

Chem Commun (Camb)

Department of Chemistry, Eastern Illinois University, Charleston, Illinois 61920, USA.

Published: October 2010

Rationally designed racemic and quasiracemic sulfonamidecinnamic acids assemble to give hydrogen-bonded dimers with coplanar alignment of neighboring olefins. The quasiracemate phase contains near inversion-related motifs with chemically distinct components forming supramolecular heterodimers that undergo asymmetric photodimerization.

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Source
http://dx.doi.org/10.1039/c0cc02775hDOI Listing

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