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Synthesis, Characterization, and Water Oxidation Activity of Isomeric Ru Complexes.
Inorg Chem
April 2021
Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.
The synthesis and characterization of the isomeric ruthenium complexes with the general formula and [Ru(trpy)(qc)X] (trpy is 2,2':6',2″-terpyridine, qc is 8-quinolinecarboxylate, and , X = Cl, = 0; and , X=OH, = 1) with respect to the relative disposition of the carboxylate and X ligands are reported. For comparison purposes, another set of ruthenium complexes with general formula and [Ru(trpy)(pic)(OH)] (pic is 2-picolinate (-, -)) have been prepared. The complexes with a qc ligand show a more distorted geometry compared to the complexes with a pic ligand.
View Article and Find Full Text PDFExperimental demonstration of radicaloid character in a Ru(V)=O intermediate in catalytic water oxidation.
Proc Natl Acad Sci U S A
March 2013
Department of Physics, Purdue University, West Lafayette, IN 47907, USA.
Water oxidation is the key half reaction in artificial photosynthesis. An absence of detailed mechanistic insight impedes design of new catalysts that are more reactive and more robust. A proposed paradigm leading to enhanced reactivity is the existence of oxyl radical intermediates capable of rapid water activation, but there is a dearth of experimental validation.
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