Single crystalline, thermally stable, Co(3)O(4) (111) holey nano-sheets were prepared by an efficient, template-free, wet chemical synthetic approach. The high energy (111) surfaces formed can be used as highly active heterogeneous catalysts for methanol decomposition.
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http://dx.doi.org/10.1039/c0nr00205d | DOI Listing |
ACS Nanosci Au
December 2024
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Acidic oxygen evolution reaction (OER) has long been the bottleneck of proton exchange membrane water electrolysis. Ru- and Ir-based oxides are currently state-of-the-art electrocatalysts for acidic OER, but their high cost limits their widespread application. CoO is a promising alternative, yet the performance requires further improvement.
View Article and Find Full Text PDFACS Omega
October 2024
Faculdade de Ciências Exatas e Tecnologia, Universidade Federal do Pará (UFPA), Abaetetuba, Pará 684440-000, Brazil.
J Environ Manage
November 2024
Department of Materials Science, University Milano Bicocca, via Cozzi 55, 20125, Milano, Italy; National Reference Center for Electrochemical Energy Storage (GISEL) - INSTM, Consorzio Interuniversitario per la Scienza e Tecnologia dei Materiali, Via Giusti 9, 50121, Firenze, Italy. Electronic address:
Lithium-ion batteries (LIBs) recycling is one of the most urgent challenges affecting this technological sector. Indeed, their continuously growing production and demand is already leading to the creation of large volumes of end-of-life LIBs (EoL-LIBs). At the same time, the growing demand for LIBs is not sustainable from the point of view of supply of the critical raw materials needed to produce the essential components of LIBs.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2024
CIDETEC, Basque Research and Technology Alliance (BRTA), Donostia-San Sebastián 20014, Spain.
The biodegradation of therapeutic magnetic-oxide nanoparticles (MONPs) in the human body raises concerns about their lifespan, functionality, and health risks. Interactions between apoferritin proteins and MONPs in the spleen, liver, and inflammatory macrophages significantly accelerate nanoparticle degradation, releasing metal ions taken up by apoferritin. This can alter the protein's biological structure and properties, potentially causing health hazards.
View Article and Find Full Text PDFACS Nano
August 2024
Department of Materials Science and Engineering, & Center of Super-Diamond and Advanced Films, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong.
Spinel cobalt oxides (CoO) have emerged as a promising class of catalysts for the electrochemical nitrate reduction reaction (eNORR) to ammonia, offering advantages such as low cost, high activity, and selectivity. However, the specific role of crystallographic facets in determining the catalysts' performance remains elusive, impeding the development of efficient catalysts. In this study, we have synthesized various CoO nanostructures with exposed facets of {100}, {111}, {110}, and {112}, aiming to investigate the dependence of the eNORR activity on the crystallographic facets.
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