AI Article Synopsis

  • The study presents a simple method for creating specific polymers that contain disulfide bonds using a technique called SET-LRP.
  • A single-step reaction allows for the reduction and connection of these polymers with functional (meth)acrylates and acrylamides.
  • This approach enables easy modifications of the polymers after their synthesis.

Article Abstract

We report the facile synthesis of well defined, disulfide containing polymers via SET-LRP. A one-pot reduction/conjugation reaction enables post polymerisation modification with functional (meth)acrylates and acrylamides.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c0cc02395gDOI Listing

Publication Analysis

Top Keywords

set-lrp one-pot
8
facile route
4
route end-functionalised
4
end-functionalised polymers
4
polymers synthesised
4
synthesised set-lrp
4
one-pot reduction/thiol-ene
4
reduction/thiol-ene michael-type
4
michael-type addition
4
addition report
4

Similar Publications

Hollow Capsules with Multiresponsive Valves for Controlled Enzymatic Reactions.

J Am Chem Soc

November 2018

Leibniz-Institut für Polymerforschung Dresden e.V. , Hohe Straße 6 , D-01069 Dresden , Germany.

The current challenge for polymeric nanoreactors is to precisely control the membrane permeability between permeable, impermeable, and semipermeable at defined pH. Additionally, the synthetic methods are obstructed by tedious purification processes, especially when polymer multiblocks are required in the membrane of capsules to achieve different responsiveness and functions. Here, we report a rapid one-pot synthesis of ABA-type triblock copolymer brushes on silica template via surface-initiated single electron transfer living radical polymerization (SI-SET-LRP).

View Article and Find Full Text PDF

A chemically unprotected mannose-containing acrylate (ManA) monomer was synthesized and polymerized by Cu(0)-mediated radical polymerization in water (SET-LRP). One-pot block copolymerization was achieved upon addition of a solution of -isopropylacrylamide (NIPAm) or diethylene glycol ethyl ether acrylate (DEGEEA) forming thermoresponsive double hydrophilic diblock glycopolymers which revealed self-assembly properties in aqueous solution forming well-defined, sugar-decorated nanoparticles.

View Article and Find Full Text PDF
Article Synopsis
  • The study presents a simple method for creating specific polymers that contain disulfide bonds using a technique called SET-LRP.
  • A single-step reaction allows for the reduction and connection of these polymers with functional (meth)acrylates and acrylamides.
  • This approach enables easy modifications of the polymers after their synthesis.
View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!