Thin, uniform, single-walled carbon nanotube films, made by a simple filtration process, subsequently coated with palladium, are shown to be promising detectors of hydrogen. The films detected hydrogen with relative responses of 20% at 100 ppm and 40% at 500 ppm concentrations. Most of the initial film conductance was recovered within 30 s by exposing the samples to air. This quick and easy recoverability make the Pd-coated nanotubes suitable for practical applications in room temperature hydrogen sensing while consuming only approximately 0.25 mW power. The film fabrication process provides highly reproducible control over the film thickness; an important ingredient for commercial production. In the course of this research strong evidence was obtained indicating that sputter deposition of metal onto the nanotubes, even under very low power, short exposure time conditions, does damage to the nanotubes.

Download full-text PDF

Source
http://dx.doi.org/10.1088/0957-4484/16/10/040DOI Listing

Publication Analysis

Top Keywords

carbon nanotube
8
nanotube films
8
room temperature
8
temperature hydrogen
8
hydrogen sensing
8
films room
4
hydrogen
4
sensing thin
4
thin uniform
4
uniform single-walled
4

Similar Publications

Strain sensing fabrics are able to sense the deformation of the outside world, bringing more accurate and real-time monitoring and feedback to users. However, due to the lack of clear sensing mechanism for high sensitivity and high linearity carbon matrix composites, the preparation of high performance strain sensing fabric weaving is still a major challenge. Here, an elastic polyurethane(PU)-based conductive fabric(GCPU) with high sensitivity, high linearity and good hydrophobicity is prepared by a novel synergistic conductive network strategy.

View Article and Find Full Text PDF

Construction of an electrochemical sensor for the detection of methyl parathion with three-dimensional graphdiyne-carbon nanotubes.

Mikrochim Acta

January 2025

CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China.

To enhance the application performance of graphdiyne (GDY) in electrochemical sensing, carbon nanotubes (CNTs) were grown in situ to construct three-dimensional nanoarchitectures of GDY-CNTs composites. GDY-CNTs showed superior electrochemical properties and detection response to MP when compared with GDY, as the in situ growth of CNTs significantly increased the electrode surface area and enhanced the electron transfer process. GDY-CNTs were successfully used to construct electrochemical sensors for methyl parathion (MP).

View Article and Find Full Text PDF

In this work, we describe a computational tool designed to determine the local dielectric constants (ε) of charge-neutral heterogeneous systems by analyzing dipole moment fluctuations from molecular dynamics (MD) trajectories. Unlike conventional methods, our tool can calculate dielectric constants for dynamically evolving selections of molecules within a defined region of space, rather than for fixed sets of molecules. We validated our approach by computing the dielectric constants of TIP3P water nanospheres, achieving results consistent with literature values for bulk water.

View Article and Find Full Text PDF

Bioinspired Photo-Thermal Catalytic System using Covalent Organic Framework-based Aerogel for Synchronous Seawater Desalination and H2O2 Production.

Angew Chem Int Ed Engl

January 2025

Nankai University, School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, CHINA.

Efficient utilization of solar energy is widely regarded as a crucial solution to addressing the energy crisis and reducing reliance on fossil fuels. Coupling photothermal and photochemical conversion can effectively improve solar energy utilization yet remains challenging. Here, inspired by the photosynthesis system in green plants, we report herein an artificial solar energy converter (ASEC) composed of light-harvesting units as solar collector and oriented ionic hydrophilic channels as reactors and transporters.

View Article and Find Full Text PDF

Towards Rational Design of Confined Catalysis in Carbon Nanotube by Machine Learning and Grand Canonical Monte Carlo Simulations.

Angew Chem Int Ed Engl

December 2024

State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, P. R. China.

The microenvironment is recognized to be as crucial as active sites in heterogeneous catalysis. It was found that the catalytic activity of a set of chemical reactions can be significantly influenced by the confined space of carbon nanotubes (CNTs), with some reactions showing superior activity, while others experience a negative impact. The rational design of confined catalysis must rely on the accurate insights of confined microenvironment.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!