A compact lanthanum hexaboride hollow cathode has been developed for space applications where size and mass are important and research and industrial applications where access for implementation might be limited. The cathode design features a refractory metal cathode tube that is easily manufactured, mechanically captured orifice and end plates to eliminate expensive e-beam welding, graphite sleeves to provide a diffusion boundary to protect the LaB6 insert from chemical reactions with the refractory metal tube, and several heater designs to provide long life. The compact LaB(6) hollow cathode assembly including emitter, support tube, heater, and keeper electrode is less than 2 cm in diameter and has been fabricated in lengths of 6-15 cm for different applications. The cathode has been operated continuously at discharge currents of 5-60 A in xenon. Slightly larger diameter versions of this design have operated at up to 100 A of discharge current.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1063/1.3474921 | DOI Listing |
RSC Adv
January 2025
Department of Nanoscience and Engineering, Center for Nano Manufacturing, Inje University 197 Inje-ro Gimhae Gyeongnam-do 50834 Republic of Korea
Recently, lithium-sulfur batteries have captivated those in the energy storage industry due to the low cost and high theoretical capacity of the sulfur cathode (1675 mA h g). However, to enhance the practical usability of Li-S batteries, it is crucial to address issues such as the insulating nature of sulfur cathodes and the high solubility of lithium polysulfides (LiPS, LiS , 4 ≤ ≤ 8) that cause poor active sulfur utilization. Designing innovative sulfur hosts can effectively overcome sulfur bottlenecks and achieve stable Li-sulfur batteries.
View Article and Find Full Text PDFMikrochim Acta
January 2025
Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province, National & Local Joint Engineering Research Center for Mineral Salt Deep Utilization, Huaiyin Institute of Technology, Huaian, 223003, P. R. China.
A highly sensitive and selective electrochemical biosensor was developed for the detection of kanamycin using a core-hollow-shell structured peroxidase-mimic nanozyme, CHS-Fe₃O₄@@ZIF-8. The synthesized CHS-FeO@@ZIF-8 was characterized with scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. It was found that the CHS-FeO@@ZIF-8 exhibits excellent peroxidase-like activity due to its ultra-thin hollow layer.
View Article and Find Full Text PDFLangmuir
January 2025
College of Textile Science and Engineering, Jiangnan University, 1800 Lihu Road, 214122 Wuxi, P. R. China.
In the realm of zinc-air batteries, high bifunctional catalytic efficacy is intimately tied to the evaluation of catalysts. Consequently, the pursuit of proficient bifunctional catalysts that can efficiently catalyze both the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) remains a paramount objective in this research area. In this study, the spiny cobalt tetroxide (CoO) encapsulated hollow carbon spheres (HCSs) are constructed by anchoring CoO onto HCS via hydrothermal or annealing treatment.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Engineering Research Center of Advanced Rare Earth Materials, Department of Chemistry, Tsinghua University, Beijing 100084, China.
The side reactions accompanying the charging and discharging process, as well as the difficulty in decomposing the discharge product lithium peroxide, have been important issues in the research field of lithium-oxygen batteries for a long time. Here, single atom Ta supported by CoO hollow sphere was designed and synthesized as a cathode catalyst. The single atom Ta forms an electron transport channel through the Ta-O-Co structure to stabilize octahedral Co sites, forming strong adsorption with reaction intermediates and ultimately forming a film-like lithium peroxide that is highly dispersed.
View Article and Find Full Text PDFSmall
January 2025
Faculty of Maritime and Transportation, Ningbo University, Ningbo, 315211, P. R. China.
Traditional hydrometallurgy methods for recycling the spent lithium-ion battery materials face some challenges, including the complex processes, and difficulties in separating Ni/Co/Mn. To address these issues, this work proposes a simple one-pot method to achieve a high Li leaching efficiency (99.2%) and simultaneously transform the majority of Ni (99.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!