We study the effective electrostatic interactions between a pair of charged colloidal particles without salt ions while the system is confined in two dimensions. In particular, we use a simplified model to elucidate the effects of rotational fluctuations in counterion distribution. The results exhibit effective colloidal attractions under appropriate conditions. Meanwhile, long-range repulsions persist over most of our studied cases. The repulsive forces arise from the fact that in two dimensions, the charged colloids cannot be perfectly screened by counterions, as the residual quadrupole moments contribute to the repulsions at longer range. By applying multiple expansions, we find that the attractive forces observed at short range are mainly contributed by electrostatic interactions among higher-order electric moments. We argue that the scenario for attractive interactions discussed in this work is applicable to systems of charged nanoparticles or colloidal solutions with macroions.
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http://dx.doi.org/10.1063/1.3474805 | DOI Listing |
Int J Biol Macromol
January 2025
School of Food Science and Technology, South China Agricultural University, Guangzhou 510642, China; School of Food Science and Technology, Jiangnan University, 1800 Lihu Road, Wuxi 214122, China; State Key Laboratory of Food Science and Resources, Jiangnan University, 1800 Lihu Road, Wuxi 214122, China. Electronic address:
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Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, School of Environmental Science and Engineering, Guangzhou University, Guangzhou, 510006, China. Electronic address:
Thallium (Tl), recognized for its high toxicity, is subject to stringent international regulations regarding its permissible concentrations at ultra-trace levels. In this study, titanium dioxide (TiO) was integrated with potassium (K)-rich biochar to create TiO/biochar (TiO/BC) composites for synergistic enhancement in ultra-trace Tl(I) removal, focusing on achieving concentration below the rigorous local threshold of 0.1 μg/L for drinking water.
View Article and Find Full Text PDFComput Biol Chem
January 2025
Department of Natural Sciences, Novosibirsk State University, Novosibirsk 630090, Russia. Electronic address:
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View Article and Find Full Text PDFPLoS One
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View Article and Find Full Text PDFIUCrJ
March 2025
Department of Chemistry, Università degli Studi di Milano, via Golgi 19, 20133 Milano, Italy.
A detailed study of the X...
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