The spin density in the nickel(II) radical salen complex (2*)(+) could be localized on a specific ring by controlling the acidity of the medium.
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Catalytic activation of C-O bonds is considered as a powerful strategy for the production of aromatics from lignin. However, due to the high reduction potentials of diaryl ether 4-O-5 linkage models, their single electron reduction remains a daunting challenge. This study presents the blue light-induced bifunctional N-heterocyclic carbene (NHC)-catalyzed one-electron reduction of diaryl ether 4-O-5 linkage models for the synthesis of trivalent phosphines.
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Institute for Inorganic Chemistry, University of Duisburg-Essen, 45117 Essen, Germany.
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Inorg Chem
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Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-nishi-machi, Nara 630-8506, Japan.
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