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Highly ordered assembly of π-stacked distyrylbenzenes by oligoadenines. | LitMetric

Highly ordered assembly of π-stacked distyrylbenzenes by oligoadenines.

Org Lett

Department of Chemistry & Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong, SAR China.

Published: September 2010

A well-defined nanofibrous structure with lengths of several hundred nanometers and cross-sectional width of a single size (∼6 ± 0.5 nm) was self-assembled by oligoadenines, dA(20), and thymine-appended distyrylbenzene through binary complementary A-T hydrogen bond formation and the strong π-π stacking interactions. This demonstrated a useful supramolecular self-assembling approach to control the packing order of π-conjugated molecules and provided a practical means to enhance the optical properties of a material.

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Source
http://dx.doi.org/10.1021/ol101571hDOI Listing

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