AI Article Synopsis
- - BaGe(5) is a new intermetallic clathrate formed when clathrate-I Ba(8)Ge(43)(3) decomposes at low temperatures.
- - Its crystal structure features unique layers that are linked together by covalent bonds.
- - BaGe(5) is classified as a semiconducting Zintl phase, which suggests it has potential applications in electronics.
Article Abstract
BaGe(5) constitutes a new type of intermetallic clathrate obtained by decomposition of clathrate-I Ba(8)Ge(43)(3) at low temperatures. The crystal structure consists of characteristic layers interconnected by covalent bonds. BaGe(5) is a semiconducting Zintl phase.
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| http://dx.doi.org/10.1021/ja104197c | DOI Listing |
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