The MixAlco process biologically converts biomass to carboxylate salts that may be converted to a variety of chemicals and fuels. This study examines the viability of different types of glycerol as a potential feedstock. Batch fermentations of crude biodiesel glycerol were compared to distilled and refined glycerol. Continuous fermentations were performed in a CSTR and a packed-bed fermentor with refined glycerol. While crude and distilled glycerol are difficult to process industrially, all types of glycerol performed well during MixAlco fermentations, producing acid concentrations above 22 g/L and conversions of greater than 65%. The CSTR configuration produced excellent acid concentrations (16 g/L) while the packed-bed configuration produced high amounts of cell material for use in cell extract products or starter cultures.
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http://dx.doi.org/10.1016/j.biortech.2010.07.041 | DOI Listing |
Sci Rep
January 2025
Bio-Circular-Green-Economy Technology and Engineering Center, BCGeTEC, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok, 10330, Thailand.
Glycerol carbonate (GC) can be produced from glycerol (GL), a low-value byproduct in the biodiesel industry. In this work, continuous processes of GC production via transesterification from crude GL and diethyl carbonate (DEC) were developed using Aspen Plus. Two cases were considered, and their process performances were compared.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Chemical Engineering, Nanjing Forestry University, Longpan Road 159, Nanjing 210037, China. Electronic address:
Glycerol is one of the most important biomass platform compounds that is a by-product of biodiesel production, and the selective cleavage of the CC bond of glycerol to produce liquid hydrogen carriers (i.e., formic acid and formaldehyde) offers a viable strategy to alleviate the currently faced energy shortages.
View Article and Find Full Text PDFHeliyon
December 2024
The Petroleum and Petrochemical College, Chulalongkorn University, Pathumwan, Bangkok 10330, Thailand.
Glycerol, a by-product of biodiesel production through transesterification, presents an opportunity for biodiesel industries to transform surplus glycerol into high-value chemical products. This study focuses on the development of a series of propyl sulfonic acid functionalized (PrSOH) SBA-15 catalysts, synthesized by direct synthesis of 3-mercaptopropyltrimethoxysilane (MPTMS) and tetraethoxysilane (TEOS) in an acidic medium. The catalysts were evaluated for acetylation of glycerol with acetic acid under conditions optimized through response surface methodology.
View Article and Find Full Text PDFJ Air Waste Manag Assoc
January 2025
Center for Applied Climate Sciences, University of Southern Queensland, Toowoomba, Australia.
Densification of biomass through pelletizing offers a promising approach to producing clean biofuels from renewable resources. This study, which investigates the impact of additive blends on wheat straw pellet making and upgrading the physiochemical properties, has revealed exciting possibilities. Five additives, including sawdust (SD), bentonite clay (BC), corn starch (S), crude glycerol (CG), and biochar (BioC), were chosen for this study.
View Article and Find Full Text PDFSci Rep
December 2024
Center of Excellence in Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok, 10330, Thailand.
Glycerol, a by-product of biodiesel production, could be converted into various value-added products. This work focuses on its dehydrogenation to dihydroxyacetone (DHA), which is mainly used in the cosmetics industry. While several methods have been employed for DHA production, some necessitate catalysts and involve harsh reaction conditions as well as long reaction times.
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