Single chain self-assembly: preparation of alpha,omega-donor-acceptor chains via living radical polymerization and orthogonal conjugation.

Chem Commun (Camb)

Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany.

Published: September 2010

Alpha,omega-hydrogen donor/acceptor functional polymer strands are prepared via a combination of living radical polymerization and orthogonal conjugation and subsequently self-assembled as single chains to emulate--on a simple level--the self-folding behaviour of natural biomacromolecules.

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http://dx.doi.org/10.1039/c0cc00702aDOI Listing

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